electromotive force of the charge, that is, to the difference of potentials of the two surfaces, and the charge corresponding to unit of electromotive force is called the capacity of the jar, a constant quantity. The corresponding quantity, which may be called the capacity of the secondary pile, increases when the electromotive force increases.
The capacity of the jar depends on the area of the opposed surfaces, on the distance between them, and on the nature of the substance between them, but not on the nature of the metallic surfaces themselves. The capacity of the secondary pile depends on the area of the surfaces of the electrodes, but not on the distance between them, and it depends on the nature of the surface of the electrodes, as well as on that of the fluid between them. The maximum difference of the potentials of the electrodes in each element of a secondary pile is very small compared with the maximum difference of the potentials of those of a charged Leyden jar, so that in order to obtain much electromotive force a pile of many elements must be used.
On the other hand, the superficial density of the charge in the secondary pile is immensely greater than the utmost superficial density of the charge which can be accumulated on the surfaces of a Leyden jar, insomuch that Mr. C. F. Varley[1], in describing the construction of a condenser of great capacity, recommends a series of gold or platinum plates immersed in dilute acid as preferable in point of cheapness to induction plates of tinfoil separated by insulating material.
The form in which the energy of a Leyden jar is stored up is the state of constraint of the dielectric between the conducting surfaces, a state which I have already described under the name of electric polarization, pointing out those phenomena attending this state which are at present known, and indicating the imperfect state of our knowledge of what really takes place. See Arts. 62, 111.
The form in which the energy of the secondary pile is stored up is the chemical condition of the material stratum at the surface of the electrodes, consisting of the ions of the electrolyte and the substance of the electrodes in a relation varying from chemical combination to superficial condensation, mechanical adherence, or simple juxtaposition.
The seat of this energy is close to the surfaces of the electrodes,
- ↑ Specification of C. F. Varley, 'Electric Telegraphs, &c.,' Jan. 1860.
