on the zinc. The zinc, copper, and fluid then form a little circuit in which rapid electrolytic action goes on, and the zinc is eaten away by an action which contributes nothing to the useful effect of the battery.
To prevent this, the zinc is immersed either in dilute sulphuric acid or in a solution of sulphate of zinc, and to prevent the solution of sulphate of copper from mixing with this liquid, the two liquids are separated by a division consisting of bladder or porous earthenware, which allows electrolysis to take place through it, but effectually prevents mixture of the fluids by visible currents.
In some batteries sawdust is used to prevent currents. The experiments of Graham, however, shew that the process of diffusion goes on nearly as rapidly when two liquids are separated by a division of this kind as when they are in direct contact, provided there are no visible currents, and it is probable that if a septum is employed which diminishes the diffusion, it will increase in exactly the same ratio the resistance of the element, because electrolytic conduction is a process the mathematical laws of which have the same form as those of diffusion, and whatever interferes with one must interfere equally with the other. The only difference is that diffusion is always going on, while the current flows only when the battery is in action.
In all forms of Daniell's battery the final result is that the sulphate of copper finds its way to the zinc and spoils the battery. To retard this result indefinitely, Sir W. Thomson[1] has constructed Darnell's battery in the following form.
In each cell the copper plate is placed horizontally at the bottom
- ↑ Proc. R. S., Jan. 19, 1871.
