Page:Collected Physical Papers.djvu/176

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156
MOLECULAR CHANGES BY ELECTRIC WAVES

damping, two opposite electric effects are induced in fatigued specimens; the positive becomes on the whole more conducting and the negative less conducting than in the fresh condition. At the inert stage the rate of mutual conversion from one state to the other probably becomes equal, and the apparent fatigue is thus not due to the absolute want of sensitiveness of the constituent varieties, but to the opposite reactions of A and B balancing each other.

We may now apply some further crucial tests to verify the suppositions made above.

Restoration of Sensitiveness to a Fatigued Substance

It was said that the inertness of the substance, after long exposure, is due to the presence of a relatively large amount of strained B variety. It therefore follows that if by any means we can transform B into A, then after such a transformation there ought to be a restoration of the sensitiveness. It has also been stated that the B variety under ordinary circumstances is less stable than A. If now we apply a disturbing cause which is unilateral in its action—that is to say, if it converts B into A and not A into B—then such a disturbing cause will re-sensitise the fatigued substance.

Effect of Mechanical Disturbance.—Of the unilateral actions, mechanical vibration is one; for it is known that by the action of friction a substance, may pass from one modification to another in one direction only. Thus the change of monoclinic into rhombic variety of sulphur is hastened by scratching with a glass rod, but the change does not take place in the opposite direction. We may now apply the crucial tests. Mechanical vibration will transform B into A. and with positive fatigued