years he entered more than 200,000 observations. His first separate publication was Meteorological Observations and Essays (1793), which contained the germs of several of his later discoveries; but in spite of the originality of its matter, the book met with only a limited sale. Another work by him, Elements of English Grammar, was published in 1801. In 1794 he was elected a member of the Manchester Literary and Philosophical Society, and a few weeks after election he communicated his first paper on “Extraordinary facts relating to the vision of colours,” in which he gave the earliest account of the optical peculiarity known as Daltonism or colour-blindness, and summed up its characteristics as observed in himself and others. Besides the blue and purple of the spectrum he was able to recognize only one colour, yellow, or, as he says in his paper, “that part of the image which others call red appears to me little more than a shade or defect of light; after that the orange, yellow and green seem one colour which descends pretty uniformly from an intense to a rare yellow, making what I should call different shades of yellow.” This paper was followed by many others on diverse topics—on rain and dew and the origin of springs, on heat, the colour of the sky, steam, the auxiliary verbs and participles of the English language and the reflection and refraction of light. In 1800 he became a secretary of the society, and in the following year he presented the important paper or series of papers, entitled “Experimental Essays on the constitution of mixed gases; on the force of steam or vapour of water and other liquids in different temperatures, both in Torricellian vacuum and in air; on evaporation; and on the expansion of gases by heat.” The second of these essays opens with the striking remark, “There can scarcely be a doubt entertained respecting the reducibility of all elastic fluids of whatever kind, into liquids; and we ought not to despair of effecting it in low temperatures and by strong pressures exerted upon the unmixed gases”; further, after describing experiments to ascertain the tension of aqueous vapour at different points between 32° and 212° F., he concludes, from observations on the vapour of six different liquids, “that the variation of the force of vapour from all liquids is the same for the same variation of temperature, reckoning from vapour of any given force.” In the fourth essay he remarks, “I see no sufficient reason why we may not conclude that all elastic fluids under the same pressure expand equally by heat and that for any given expansion of mercury, the corresponding expansion of air is proportionally something less, the higher the temperature. . . . It seems, therefore, that general laws respecting the absolute quantity and the nature of heat are more likely to be derived from elastic fluids than from other substances.” He thus enunciated the law of the expansion of gases, stated some months later by Gay-Lussac. In the two or three years following the reading of these essays, he published several papers on similar topics, that on the “Absorption of gases by water and other liquids” (1803), containing his “Law of partial pressures.”
But the most important of all Dalton’s investigations are those concerned with the Atomic Theory in chemistry, with which his name is inseparably associated. It has been supposed that this theory was suggested to him either by researches on olefiant gas and carburetted hydrogen or by analysis of “protoxide and deutoxide of azote,” both views resting on the authority of Dr Thomas Thomson (1773–1852), professor of chemistry in Glasgow university. But from a study of Dalton’s own MS. laboratory notebooks, discovered in the rooms of the Manchester society, Roscoe and Harden (A New View of the Origin of Dalton’s Atomic Theory, 1896) conclude that so far from Dalton being led to the idea that chemical combination consists in the approximation of atoms of definite and characteristic weight by his search for an explanation of the law of combination in multiple proportions, the idea of atomic structure arose in his mind as a purely physical conception, forced upon him by study of the physical properties of the atmosphere and other gases. The first published indications of this idea are to be found at the end of his paper on the “Absorption of gases” already mentioned, which was read on the 21st of October 1803 though not published till 1805. Here he says: “Why does not water admit its bulk of every kind of gas alike? This question I have duly considered, and though I am not able to satisfy myself completely I am nearly persuaded that the circumstance depends on the weight and number of the ultimate particles of the several gases.” He proceeds to give what has been quoted as his first table of atomic weights, but on p. 248 of his laboratory notebooks for 1802–1804, under the date 6th of September 1803, there is an earlier one in which he sets forth the relative weights of the ultimate atoms of a number of substances, derived from analysis of water, ammonia, carbon-dioxide, &c. by chemists of the time. It appears, then, that, confronted with the “problem of ascertaining the relative diameter of the particles of which, he was convinced, all gases were made up, he had recourse to the results of chemical analysis. Assisted by the assumption that combination always takes place in the simplest possible way, he thus arrived at the idea that chemical combination takes place between particles of different weights, and this it was which differentiated his theory from the historic speculations of the Greeks. The extension of this idea to substances in general necessarily led him to the law of combination in multiple proportions, and the comparison with experiment brilliantly confirmed the truth of his deduction” (A New View, &c., pp. 50, 51). It may be noted that in a paper on the “Proportion of the gases or elastic fluids constituting the atmosphere,” read by him in November 1802, the law of multiple proportions appears to be anticipated in the words—“The elements of oxygen may combine with a certain portion of nitrous gas or with twice that portion, but with no intermediate quantity,” but there is reason to suspect that this sentence was added some time after the reading of the paper, which was not published till 1805.
Dalton communicated his atomic theory to Dr Thomson, who by consent included an outline of it in the third edition of his System of Chemistry (1807), and Dalton gave a further account of it in the first part of the first volume of his New System of Chemical Philosophy (1808). The second part of this volume appeared in 1810, but the first part of the second volume was not issued till 1827, though the printing of it began in 1817. This delay is not explained by any excess of care in preparation, for much of the matter was out of date and the appendix giving the author’s latest views is the only portion of special interest. The second part of vol. ii. never appeared.
Altogether Dalton contributed 116 memoirs to the Manchester Literary and Philosophical Society, of which from 1817 till his death he was the president. Of these the earlier are the most important. In one of them, read in 1814, he explains the principles of volumetric analysis, in which he was one of the earliest workers. In 1840 a paper on the phosphates and arsenates, which was clearly unworthy of him, was refused by the Royal Society, and he was so incensed that he published it himself. He took the same course soon afterwards with four other papers, two of which—“On the quantity of acids, bases and salts in different varieties of salts” and “On a new and easy method of analysing sugar,” contain his discovery, regarded by him as second in importance only to the atomic theory, that certain anhydrous salts when dissolved in water cause no increase in its volume, his inference being that the “salt enters into the pores of the water.”
As an investigator, Dalton was content with rough and inaccurate instruments, though better ones were readily attainable. Sir Humphry Davy described him as a “very coarse experimenter,” who “almost always found the results he required, trusting to his head rather than his hands.” In the preface to the second part of vol. i. of his New System he says he had so often been misled by taking for granted the results of others that he “determined to write as little as possible but what I can attest by my own experience,” but this independence he carried so far that it sometimes resembled lack of receptivity. Thus he distrusted, and probably never fully accepted, Gay-Lussac’s conclusions as to the combining volumes of gases; he held peculiar and quite unfounded views about chlorine, even after
