electricity on the surface of a cylinder, and its distribution between a sphere and cylinder of different lengths but of the same diameter. His experiments on the dissipation of electricity possess also a high value. He found that the momentary dissipation was proportional to the degree of electrification at the time, and that, when the charge was moderate, its dissipation was not altered in bodies of different kinds or shapes. The temperature and pressure of the atmosphere did not produce any sensible change; but he concluded that the dissipation was nearly proportional to the cube of the quantity of moisture in the air.[1] In examining the dissipation which takes place along imperfectly insulating substances, he found that a thread of gum-lac was the most perfect of all insulators; that it insulated ten times as well as a dry silk thread; and that a silk thread covered with fine sealing-wax insulated as powerfully as gum-lac when it had four times its length. He found also that the dissipation of electricity along insulators was chiefly owing to adhering moisture, but in some measure also to a slight conducting power. For his memoirs see Mém. de math. et phys. de l’acad. de sc., 1785, &c.
Second Period.—We now enter upon the second period of electrical research inaugurated by the epoch-making discovery of Alessandro Volta (1745–1827). L. Galvani had made in 1790 his historic observations on the muscular contraction produced in the bodies of recently killed frogs when an electrical machine was being worked in the same room, and described them in 1791 (De viribus electricitatis in motu musculari commentarius, Bologna, 1791). Volta followed up these observations with rare philosophic insight and experimental skill. He showed that all conductors liquid and solid might be divided into two classes which he called respectively conductors of the first and of the second class, the first embracing metals and carbon in its conducting form, and the second class, water, aqueous solutions of various kinds, and generally those now called electrolytes. In the case of conductors of the first class he proved by the use of the condensing electroscope, aided probably by some form of multiplier or doubler, that a difference of potential (see Electrostatics) was created by the mere contact of two such conductors, one of them being positively electrified and the other negatively. Volta showed, however, that if a series of bodies of the first class, such as disks of various metals, are placed in contact, the potential difference between the first and the last is just the same as if they are immediately in contact. There is no accumulation of potential. If, however, pairs of metallic disks, made, say, of zinc and copper, are alternated with disks of cloth wetted with a conductor of the second class, such, for instance, as dilute acid or any electrolyte, then the effect of the feeble potential difference between one pair of copper and zinc disks is added to that of the potential difference between the next pair, and thus by a sufficiently long series of pairs any required difference of potential can be accumulated.
The Voltaic Pile.—This led him about 1799 to devise his famous voltaic pile consisting of disks of copper and zinc or other metals with wet cloth placed between the pairs. Numerous examples of Volta’s original piles at one time existed in Italy, and were collected together for an exhibition held at Como in 1899, but were unfortunately destroyed by a disastrous fire on the 8th of July 1899. Volta’s description of his pile was communicated in a letter to Sir Joseph Banks, president of the Royal Society of London, on the 20th of March 1800, and was printed in the Phil. Trans., vol. 90, pt. 1, p. 405. It was then found that when the end plates of Volta’s pile were connected to an electroscope the leaves diverged either with positive or negative electricity. Volta also gave his pile another form, the couronne des tasses (crown of cups), in which connected strips of copper and zinc were used to bridge between cups of water or dilute acid. Volta then proved that all metals could be arranged in an electromotive series such that each became positive when placed in contact with the one next below it in the series. The origin of the electromotive force in the pile has been much discussed, and Volta’s discoveries gave rise to one of the historic controversies of science. Volta maintained that the mere contact of metals was sufficient to produce the electrical difference of the end plates of the pile. The discovery that chemical action was involved in the process led to the advancement of the chemical theory of the pile and this was strengthened by the growing insight into the principle of the conservation of energy. In 1851 Lord Kelvin (Sir W. Thomson), by the use of his then newly-invented electrometer, was able to confirm Volta’s observations on contact electricity by irrefutable evidence, but the contact theory of the voltaic pile was then placed on a basis consistent with the principle of the conservation of energy. A. A. de la Rive and Faraday were ardent supporters of the chemical theory of the pile, and even at the present time opinions of physicists can hardly be said to be in entire accordance as to the source of the electromotive force in a voltaic couple or pile.[2]
Improvements in the form of the voltaic pile were almost immediately made by W. Cruickshank (1745–1800), Dr W. H. Wollaston and Sir H. Davy, and these, together with other eminent continental chemists, such as A. F. de Fourcroy, L. J. Thénard and J. W. Ritter (1776–1810), ardently prosecuted research with the new instrument. One of the first discoveries made with it was its power to electrolyse or chemically decompose certain solutions. William Nicholson (1753–1815) and Sir Anthony Carlisle (1768–1840) in 1800 constructed a pile of silver and zinc plates, and placing the terminal wires in water noticed the evolution from these wires of bubbles of gas, which they proved to be oxygen and hydrogen. These two gases, as Cavendish and James Watt had shown in 1784, were actually the constituents of water. From that date it was clearly recognized that a fresh implement of great power had been given to the chemist. Large voltaic piles were then constructed by Andrew Crosse (1784–1855) and Sir H. Davy, and improvements initiated by Wollaston and Robert Hare (1781–1858) of Philadelphia. In 1806 Davy communicated to the Royal Society of London a celebrated paper on some “Chemical Agencies of Electricity,” and after providing himself at the Royal Institution of London with a battery of several hundred cells, he announced in 1807 his great discovery of the electrolytic decomposition of the alkalis, potash and soda, obtaining therefrom the metals potassium and sodium. In July 1808 Davy laid a request before the managers of the Royal Institution that they would set on foot a subscription for the purchase of a specially large voltaic battery; as a result he was provided with one of 2000 pairs of plates, and the first experiment performed with it was the production of the electric arc light between carbon poles. Davy followed up his initial work with a long and brilliant series of electrochemical investigations described for the most part in the Phil. Trans. of the Royal Society.
Magnetic Action of Electric Current.—Noticing an analogy between the polarity of the voltaic pile and that of the magnet, philosophers had long been anxious to discover a relation between the two, but twenty years elapsed after the invention of the pile before Hans Christian Oersted (1777–1851), professor of natural philosophy in the university of Copenhagen, made in 1819 the discovery which has immortalized his name. In the Annals of Philosophy (1820, 16, p. 273) is to be found an English translation of Oersted’s original Latin essay (entitled “Experiments on the Effect of a Current of Electricity on the Magnetic Needle”), dated the 21st of July 1820, describing his discovery. In it Oersted describes the action he considers is taking place around
- ↑ Modern researches have shown that the loss of charge is in fact dependent upon the ionization of the air, and that, provided the atmospheric moisture is prevented from condensing on the insulating supports, water vapour in the air does not per se bestow on it conductance for electricity.
- ↑ Faraday discussed the chemical theory of the pile and arguments in support of it in the 8th and 16th series of his Experimental Researches on Electricity. De la Rive reviews the subject in his large Treatise on Electricity and Magnetism, vol. ii. ch. iii. The writer made a contribution to the discussion in 1874 in a paper on “The Contact Theory of the Galvanic Cell,” Phil. Mag., 1874, 47, p. 401. Sir Oliver Lodge reviewed the whole position in a paper in 1885. “On the Seat of the Electromotive Force in a Voltaic Cell,” Journ. Inst. Elec. Eng., 1885, 14, p. 186.
