Paris Exhibition of 1878 bricks very hard and dense in character,
said to be of pure alumina, were exhibited by Muller & Co. of
Paris, as well as bricks of magnesia, the latter being specially
remarkable for their great weight. They are intended for use
at the extreme temperatures obtainable in steel furnaces, or
for the melting of platinum before the oxy-hydrogen blowpipe.
For the latter purpose, however, lime is generally used; but as
this substance has only small stability, it is usually bedded in a
casing of firebrick. Oxide of chromium and chrome iron ore
have been proposed as refractory crucible materials. The former
may be used as a bed for melting platinum in the same way as
lime or magnesia, without affecting the quality of the metal.
Ferric oxide, though not strictly infusible, is largely used as a protecting lining for furnaces in which malleable iron is made, a portion of the ore being reduced and recovered in the process. In an oxidizing atmosphere it is indifferent to silica, and therefore siliceous bricks containing a considerable proportion of ferric oxide, when used in flues of boilers, brewers’ coppers, &c. and similar situations, are perfectly fire-resisting so long as the heated gas contains a large proportion of unconsumed air. The red firebricks known as Windsor bricks, which are practically similar in composition to soft red sandstone, are of this character.
The electric furnace has led to the discovery of several important materials, which have been employed as furnace linings. Carborundum (q.v.) was applied by Engels in 1899, firebricks being washed with carborundum paste and then baked. Siloxicon, a compound of carbon, silicon and oxygen, formed from carbon and silica in the electric furnace, was patented by E. G. Acheson in 1903. It is very refractory, and is applied by mixing with water and some bond, such as sodium silicate or gas-tar. An amorphous, soft silicon carbide, also formed in the electric furnace, was patented by B. Talbot in 1899. For basic linings, magnesia crystallized in the electric furnace is being extensively used, replacing dolomite to some extent (see E. Kilburn Scott, “Refractory Materials for Furnace Linings,” Faraday Soc., 1906, p. 289).
Furnace Construction.—In the construction of furnaces provision has to be made for the unequal expansion of the different parts under the effect of heat. This is especially necessary in the case of reverberatory furnaces, which are essentially weak structures, and therefore require to be bound together by complicated systems of tie rods and uprights or buck staves. The latter are very commonly made of old flat bottom rails, laid with the flat of the flange against the wall. Puddling furnaces are usually entirely cased with iron plates, and blast furnaces with hoops round each course of the stack, or in those of thinner constructions the firebrick work is entirely enclosed in a wrought iron casing or jacket. Such parts as may be subjected to extreme heat and the fretting action of molten material, as the tuyere and slag breasts of blast furnaces, and the fire bridges and bed plates of reverberatory furnaces, are often made in cast iron with double walls, a current of water or air being kept circulating through the intermediate space. In this way the metal, owing to its high conductivity and low specific heat as compared to that of water, is kept at a temperature far below its melting point if the water is renewed quickly enough. It is of course necessary in such cases that the circulation shall be perfectly free, in order to prevent the accumulation of steam under pressure in the interior of the casting. This method has received considerable extension, notably in furnace-smelting of iron ores containing manganese, where the entire hearth is often completely water-cased, and in some lead furnaces where no firebrick lining is used, the lower part of the furnace stack being a mere double iron box cooled by water sufficiently to keep a coating of slag adhering to the inner shell which prevents the metal from being acted upon.
Mechanical Furnaces.—The introduction and withdrawal of the charges in fusion furnaces is effected by gravitation, the solid masses of raw ore, fuel and flux being thrown in at the top, and flowing out of the furnace at the taphole or slag run at the bottom. Vertical kilns, such as those used for burning limestone, are worked in a similar manner—the raw stone going in at the top, and the burnt product falling through holes in the bottom when allowed to do so. With reverberatory calciners, however, where the work is done upon a horizontal bed, a considerable amount of hand labour is expended in raking out the charge when finished, and in drawing slags from fusion furnaces; and more particularly in the puddling process of refining iron the amount of manual exertion required is very much greater. To diminish the item of expenditure on this head, various kinds of mechanical furnaces have been adopted, all of which can be classified under three heads of gravitating furnaces, mechanical stirrers and revolving furnaces.
1. In gravitating furnaces the bed is laid at a slope just within the angle of repose of the charge, which is introduced at the upper end, and is pushed down the slope by fresh material, when necessary, in the contrary direction to the flame which enters at the lower end. Gerstenhofer’s pyrites burner is a furnace of this class. It has a tall vertical chamber heated from below, and traversed by numerous narrow horizontal cross bars at different heights. The ore in fine powder is fed in at the top, through a hopper, in a regular thin stream, by a pair of rollers, and in falling lodges on the flats of the bars, forming a talus upon each of the height corresponding to the angle of rest of the material, which is, however, at short intervals removed to lower levels by the arrival of fresh ore from above. In this way a very large surface is exposed to the heat, and the ore, if containing sufficient sulphur to maintain the combustion, is perfectly burned when it arrives at the bottom; if, however, it is imperfectly sized or damp, or if it contains much earthy matter, the result is not very satisfactory. There are many other furnaces in which the same principle is utilized.
2. Mechanical stirrers constitute a second division of mechanical furnaces, in which the labour of rabbling or stirring the charges is performed by combinations of levers and wheel-work taking motion from a rotating shaft, and more or less perfectly imitating the action of hand labour. They are almost entirely confined to puddling furnaces.
3. Revolving furnaces, the third and most important division of mechanical furnaces, are of two kinds. The first of these resemble an ordinary reverberatory furnace by having a flat bed which, however, has the form of a circular disk mounted on a central shaft, and receives a slow movement of rotation from a water-wheel or other motor, so that every part of the surface is brought successively under the action of the fire, the charge being stirred and ultimately removed by passing under a series of fixed scraper arms placed above the surface at various points. Brunton’s calciner, used in the “burning” of the pyritic minerals associated with tin ore, is a familiar example of this type. The hearth may either rotate on an inclined axis, so that the path of its surface is oblique to that of the flame, or the working part may be a hollow cylinder, between the fireplace and flue, with its axis horizontal or nearly so, whose inner surface represents the working bed, mounted upon friction rollers, and receiving motion from a special steam-engine by means of a central belt of spur gearing. Furnaces of the second kind were first used in alkali works for the conversion of sulphate into carbonate of sodium in the process known as black ash fusion, but have since been applied to other processes. As calciners they are used in tin mines and for the chlorination of silver ores. Mechanical furnaces are figured in the article Alkali Manufacture.
Use of Heated Air.—The calorific intensity of fuel is found to be very considerably enhanced, if the combustion be effected with air previously heated to any temperature between that of boiling water and a dull red heat, the same effect being observed both with solid and gaseous fuel. The latter, especially when brought to the burning point at a high temperature, produces a heat that can be resisted by the most refractory substances only, such as silica, alumina and magnesia. This is attained in the regenerative furnace of Siemens, detailed consideration of which belongs more properly to the subject of iron.
Economy of Waste Heat.—In every system of artificial heating, the amount of heat usefully applied is but a small proportion of that developed by combustion. Even under the most advantageous application, that of evaporation of water in a steam boiler where the gases of the fire have to travel through a great length of flues bounded by thin iron surfaces of great heat-absorbing capacity, the temperature of the current at the chimney is generally much above that required to maintain an active draught in the fireplace; and other tubes containing water, often in considerable numbers, forming the so-called fuel economizers, may often be interposed between the boiler and the chimney with marked advantage as regards saving of fuel. In reverberatory and air furnaces used in the different operations of iron manufacture, where an extremely high temperature has to be maintained in spaces of comparatively small extent, such as the beds of puddling, welding and steel-melting furnaces, the temperature of the exhaust gases is exceedingly high, and if allowed to pass directly into the chimney they appear as a great body of flame at the top. It is now general to save a portion of this heat by passing the flame through flues of steam boilers, air-heating apparatus, or both—so that the steam required for the necessary operations of the forge and heated blast for the furnace itself may be obtained without further expenditure of fuel. The most perfect method of utilizing the waste heat hitherto applied is that of the Siemens regenerator, in which the spent gases are made to travel through chambers, known as regenerators or recuperators of heat, containing a quantity of thin firebricks piled into a cellular mass so as to offer a very large heat-absorbing surface, whereby their temperature is very considerably reduced, and they arrive at the chimney at a heat not exceeding 300 or 400 degrees. As soon as the bricks have become red hot, the current is diverted to an adjacent chamber or pair of chambers, and the acquired heat is removed by a current of cool gas or air passing towards the furnace, where it arrives at a temperature sufficiently high to ensure the greatest possible heating effect in combustion.
