them. All such losses are supposed to be absent in deducing the
ideal limit of efficiency, beyond which it would be impossible
to go.
14. Carnot’s Description of his Ideal Cycle.—Carnot first gives a rough illustration of an incomplete cycle, using steam much in the same way as it is employed in an ordinary steam-engine. After expansion down to condenser pressure the steam is completely condensed to water, and is then returned as cold water to the hot boiler. He points out that the last step does not conform exactly to the condition he laid down, because although the water is restored to its initial state, there is direct passage of heat from a hot body to a cold body in the last process. He points out that this difficulty might be overcome by supposing the difference of temperature small, and by employing a series of engines, each working through a small range, to cover a finite interval of temperature. Having established the general notions of a perfect cycle, he proceeds to give a more exact illustration, employing a gas as the working substance. He takes as the basis of his demonstration the well-established experimental fact that a gas is heated by rapid compression and cooled by rapid expansion, and that if compressed or expanded slowly in contact with conducting bodies, the gas will give out heat in compression or absorb heat in expansion while its temperature remains constant. He then goes on to say:—
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| Fig 4. Carnot’s Cylinder. |
“This preliminary notion being settled, let us imagine an elastic fluid, atmospheric air for example, enclosed in a cylinder abcd, fig. 4, fitted with a movable diaphragm or piston cd. Let there also be two bodies A, B, each maintained at a constant temperature, that of A being more elevated than that of B. Let us now suppose the following series of operations to be performed:
“1. Contact of the body A with the air contained in the space abcd, or with the bottom of the cylinder, which we will suppose to transmit heat easily. The air is now at the temperature of the body A, and cd is the actual position of the piston.
“2. The piston is gradually raised, and takes the position ef. The air remains in contact with the body A, and is thereby maintained at a constant temperature during the expansion. The body A furnishes the heat necessary to maintain the constancy of temperature.
“3. The body A is removed, and the air no longer being in contact with any body capable of giving it heat, the piston continues nevertheless to rise, and passes from the position ef to gh. The air expands without receiving heat and its temperature falls. Let us imagine that it falls until it is just equal to that of the body B. At this moment the piston is stopped and occupies the position gh.
“4. The air is placed in contact with the body B; it is compressed by the return of the piston, which is brought from the position gh to the position cd. The air remains meanwhile at a constant temperature, because of its contact with the body B to which it gives up its heat.
“5. The body B is removed, and the compression of the air is continued. The air being now isolated, rises in temperature. The compression is continued until the air has acquired the temperature of the body A. The piston passes meanwhile from the position cd to the position ik.
“6. The air is replaced in contact with the body A, and the piston returns from the position ik to the position ef, the temperature remaining invariable.
“7. The period described under (3) is repeated, then successively the periods (4), (5), (6); (3), (4), (5), (6); (3), (4), (5), (6); and so on.
“During these operations the air enclosed in the cylinder exerts an effort more or less great on the piston. The pressure of the air varies both on account of changes of volume and on account of changes of temperature; but it should be observed that for equal volumes, that is to say, for like positions of the piston, the temperature is higher during the dilatation than during the compression. Since the pressure is greater during the expansion, the quantity of motive power produced by the dilatation is greater than that consumed by the compression. We shall thus obtain a balance of motive power, which may be employed for any purpose. The air has served as working substance in a heat-engine; it has also been employed in the most advantageous manner possible, since no useless re-establishment of the equilibrium of heat has been allowed to occur.
“All the operations above described may be executed in the reverse order and direction. Let us imagine that after the sixth period, that is to say, when the piston has reached the position ef, we make it return to the position ik, and that at the same time we keep the air in contact with the hot body A; the heat furnished by this body during the sixth period will return to its source, that is, to the body A, and everything will be as it was at the end of the fifth period. If now we remove the body A, and if we make the piston move from ik to cd, the temperature of the air will decrease by just as many degrees as it increased during the fifth period, and will become that of the body B. We can evidently continue in this way a series of operations the exact reverse of those which were previously described; it suffices to place oneself in the same circumstances and to execute for each period a movement of expansion in place of a movement of compression, and vice versa.
“The result of the first series of operations was the production of a certain quantity of motive power, and the transport of heat from the body A to the body B; the result of the reverse operations is the consumption of the motive power produced in the first case, and the return of heat from the body B to the body A, in such sort that these two series of operations annul and neutralize each other.
“The impossibility of producing by the agency of heat alone a quantity of motive power greater than that which we have obtained in our first series of operations is now easy to prove. It is demonstrated by reasoning exactly similar to that which we have already given. The reasoning will have in this case a greater degree of exactitude; the air of which we made use to develop the motive power is brought back at the end of each cycle of operations precisely to its initial state, whereas this was not quite exactly the case for the vapour of water, as we have already remarked.”
15. Proof of Carnot’s Principle.—Carnot considered the proof too obvious to be worth repeating, but, unfortunately, his previous demonstration, referring to an incomplete cycle, is not so exactly worded that exception cannot be taken to it. We will therefore repeat his proof in a slightly more definite and exact form. Suppose that a reversible engine R, working in the cycle above described, takes a quantity of heat H from the source in each cycle, and performs a quantity of useful work Wr. If it were possible for any other engine S, working with the same two bodies A and B as source and refrigerator, to perform a greater amount of useful work Ws per cycle for the same quantity of heat H taken from the source, it would suffice to take a portion Wr of this motive power (since Ws is by hypothesis greater than Wr) to drive the engine R backwards, and return a quantity of heat H to the source in each cycle. The process might be repeated indefinitely, and we should obtain at each repetition a balance of useful work Ws − Wr, without taking any heat from the source, which is contrary to experience. Whether the quantity of heat taken from the condenser by R is equal to that given to the condenser by S is immaterial. The hot body A might be a comparatively small boiler, since no heat is taken from it. The cold body B might be the ocean, or the whole earth. We might thus obtain without any consumption of fuel a practically unlimited supply of motive power. Which is absurd.
Carnot’s Statement of his Principle.[1]—If the above reasoning be admitted, we must conclude with Carnot that the motive power obtainable from heat is independent of the agents employed to realize it. The efficiency is fixed solely by the temperatures of the bodies between which, in the last resort, the transfer of heat is effected. “We must understand here that each of the methods of developing motive power attains the perfection of which it is susceptible. This condition is fulfilled if, according to our rule, there is produced in the body no change of temperature that is not due to change of volume, or in other words, if there is no direct interchange of heat between bodies of sensibly different temperatures.”
It is characteristic of a state of frictionless mechanical equilibrium that an indefinitely small difference of pressure suffices to upset the equilibrium and reverse the motion. Similarly in thermal equilibrium between bodies at the same temperature, an indefinitely small difference of temperature suffices to reverse the transfer of heat. Carnot’s rule is therefore the criterion of the reversibility of a cycle of operations as regards transfer of heat. It is assumed that the ideal engine is mechanically
- ↑ Carnot’s description of his cycle and statement of his principle have been given as nearly as possible in his own words, because some injustice has been done him by erroneous descriptions and statements.
