he assigned to dephlogisticated air the name oxygen, or “acid-producer,” on the supposition that all acids were formed by its union with a simple, usually non-metallic, body; and having verified this notion for phosphorus, sulphur, charcoal, &c., and even extended it to the vegetable acids, he naturally asked himself what was formed by the combustion of “inflammable air” (hydrogen). This problem he had attacked in 1774, and in subsequent years he made various attempts to discover the acid which, under the influence of his oxygen theory, he expected would be formed. It was not till the 25th of June 1783 that in conjunction with Laplace he announced to the Academy that water was the product formed by the combination of hydrogen and oxygen, but by that time he had been anticipated by Cavendish, to whose prior work, however, as to that of several other investigators in other matters, it is to be regretted that he did not render due acknowledgment. But a knowledge of the composition of water enabled him to storm the last defences of the phlogistonists. Hydrogen they held to be the phlogiston of metals, and they supported this view by pointing out that it was liberated when metals were dissolved in acids. Considerations of weight had long prevented Lavoisier from accepting this doctrine, but he was now able to explain the process fully, showing that the hydrogen evolved did not come from the metal itself, but was one product of the decomposition of the water of the dilute acid, the other product, oxygen, combining with the metal to form an oxide which in turn united with the acid. A little later this same knowledge led him to the beginnings of quantitative organic analysis. Knowing that the water produced by the combustion of alcohol was not pre-existent in that substance but was formed by the combination of its hydrogen with the oxygen of the air, he burnt alcohol and other combustible organic substances, such as wax and oil, in a known volume of oxygen, and, from the weight of the water and carbon dioxide produced and his knowledge of their composition, was able to calculate the amounts of carbon, hydrogen and oxygen present in the substance.
Up to about this time Lavoisier’s work, mainly quantitative in character, had appealed most strongly to physicists, but it now began to win conviction from chemists also. C. L. Berthollet, L. B. Guyton de Morveau and A. F. Fourcroy, his collaborators in the reformed system of chemical terminology set forth in 1787 in the Méthode de nomenclature chimique, were among the earliest French converts, and they were followed by M. H. Klaproth and the German Academy, and by most English chemists except Cavendish, who rather suspended his judgment, and Priestley, who stubbornly clung to the opposite view. Indeed, though the partisans of phlogiston did not surrender without a struggle, the history of science scarcely presents a second instance of a change so fundamental accomplished with such ease. The spread of Lavoisier’s doctrines was greatly facilitated by the defined and logical form in which he presented them in his Traité élémentaire de chimie (présenté dans un ordre nouveau et d’après les découvertes modernes) (1789). The list of simple substances contained in the first volume of this work includes light and caloric with oxygen, azote and hydrogen. Under the head of “oxidable or acidifiable” substances, the combination of which with oxygen yielded acids, were placed sulphur, phosphorus, carbon, and the muriatic, fluoric and boracic radicles. The metals, which by combination with oxygen became oxides, were antimony, silver, arsenic, bismuth, cobalt, copper, tin, iron, manganese, mercury, molybdenum, nickel, gold, platinum, lead, tungsten and zinc; and the “simple earthy salifiable substances” were lime, baryta, magnesia, alumina and silica. The simple nature of the alkalies Lavoisier considered so doubtful that he did not class them as elements, which he conceived as substances which could not be further decomposed by any known process of analysis—les molécules simples et indivisibles qui composent les corps. The union of any two of the elements gave rise to binary compounds, such as oxides, acids, sulphides, &c. A substance containing three elements was a binary compound of the second order; thus salts, the most important compounds of this class, were formed by the union of acids and oxides, iron sulphate, for instance, being a compound of iron oxide with sulphuric acid.
In addition to his purely chemical work, Lavoisier, mostly in conjunction with Laplace, devoted considerable attention to physical problems, especially those connected with heat. The two carried out some of the earliest thermochemical investigations, devised apparatus for measuring linear and cubical expansions, and employed a modification of Joseph Black’s ice calorimeter in a series of determinations of specific heats. Regarding heat (matière de feu or fluide igné) as a peculiar kind of imponderable matter, Lavoisier held that the three states of aggregation—solid, liquid and gas—were modes of matter, each depending on the amount of matière de feu with which the ponderable substances concerned were interpenetrated and combined; and this view enabled him correctly to anticipate that gases would be reduced to liquids and solids by the influence of cold and pressure. He also worked at fermentation, respiration and animal heat, looking upon the processes concerned as essentially chemical in nature. A paper discovered many years after his death showed that he had anticipated later thinkers in explaining the cyclical process of animal and vegetable life, for he pointed out that plants derive their food from the air, from water, and in general from the mineral kingdom, and animals in turn feed on plants or on other animals fed by plants, while the materials thus taken up by plants and animals are restored to the mineral kingdom by the breaking-down processes of fermentation, putrefaction and combustion.
A complete edition of the writings of Lavoisier, Œuvres de Lavoisier, publiées par les soins du ministre de l’instruction publique, was issued at Paris in six volumes from 1864–1893. This publication comprises his Opuscules physiques et chimiques (1774), many memoirs from the Academy volumes, and numerous letters, notes and reports relating to the various matters on which he was engaged. At the time of his death he was preparing an edition of his collected works, and the portions ready for the press were published in two volumes as Mémoires de chimie in 1805 by his widow (in that year married to Count Rumford), who had drawn and engraved the plates in his Traité élémentaire de chimie (1789).
See E. Grimaux, Lavoisier 1743–1794, d’après sa correspondance, ses manuscripts, &c. (1888), which gives a list of his works; P. E. M. Berthelot, La Révolution chimique: Lavoisier (1890), which contains an analysis of and extracts from his laboratory notebooks.
LA VOISIN. Catherine Monvoisin, known as “La Voisin” (d. 1680), French sorceress, whose maiden name was Catherine Deshayes, was one of the chief personages in the famous affaire des poisons, which disgraced the reign of Louis XIV. Her husband, Monvoisin, was an unsuccessful jeweller, and she practised chiromancy and face-reading to retrieve their fortunes. She gradually added the practice of witchcraft, in which she had the help of a renegade priest, Étienne Guibourg, whose part was the celebration of the “black mass,” an abominable parody in which the host was compounded of the blood of a little child mixed with horrible ingredients. She practised medicine, especially midwifery, procured abortion and provided love powders and poisons. Her chief accomplice was one of her lovers, the magician Lesage, whose real name was Adam Cœuret. The great ladies of Paris flocked to La Voisin, who accumulated enormous wealth. Among her clients were Olympe Mancini, comtesse de Soissons, who sought the death of the king’s mistress, Louise de la Vallière; Mme de Montespan, Mme de Gramont (la belle Hamilton) and others. The bones of toads, the teeth of moles, cantharides, iron filings, human blood and human dust were among the ingredients of the love powders concocted by La Voisin. Her knowledge of poisons was not apparently so thorough as that of less well-known sorcerers, or it would be difficult to account for La Vallière’s immunity. The art of poisoning had become a regular science. The death of Henrietta, duchess of Orleans, was attributed, falsely it is true, to poison, and the crimes of Marie Madeleine de Brinvilliers (executed in 1676) and her accomplices were still fresh in the public mind. In April 1679 a commission appointed to inquire into the subject and to prosecute the offenders met for the first time. Its proceedings, including some suppressed in the official records, are preserved in the notes of one of the official rapporteurs, Gabriel Nicolas de la Reynie. The revelation of the treacherous intention
