peculiar material, and may be completely washed out of a leather tanned with it. It mellows exceedingly, and keeps the leather fibre open; it may be said that it only goes in the leather to prepare and make easy the way for other tannins. Block gambier contains from 35% to 40% and cube gambier from 50% to 65% of tannin.
Hemlock generally reaches the market as extract, prepared from the bark of the American tree. It contains about 22% of tannin, has a pine-like odour, but yields a rather dark-coloured red leather.
Quebracho is imported mainly as solid extract, containing 63% to 70% of tannin; it is a harsh, light-red tannage, but darkens rapidly on exposure to light. It is used for freshening up very mellow liquors, but is rather wasteful, as it deposits an enormous amount of its tannin as phlobaphenes.
Mangrove or cutch is a solid extract prepared from the mangrove tree found in the swamps of Borneo and the Straits Settlements; it contains upwards of 60% of a red tannin.
Mimosa is the bark of the Australian golden wattle (Acacia pycnantha), and contains from 36% to 50% of tannin. It is a rather harsh tannage, yielding a flesh-coloured leather, and is useful for sharpening liquors. This bark is now successfully cultivated in Natal. The tannin content of this Natal bark is somewhat inferior, but the colour is superior to the Australian product.
Larch bark contains 9% to 10% of light-coloured tannin, and is used especially for tanning Scotch basils.
Canaigre is the air-dried tuberous roots of a Mexican plant, containing 25% to 30% of tannin and about 8% of starch. It yields an orange-coloured leather of considerable weight and firmness. Its cultivation did not pay well enough, so that it is little used.
Cutch, catechu or “dark catechu,” is obtained from the wood of Indian acacias, and is not to be confounded with mangrove cutch. It contains 60% of tanning matter and a large proportion of catechin similar to that contained in gambier, but much redder. It is used for dyeing browns and blacks with chrome and iron mordants.
The willow and the white birch barks contain, respectively, 12% to 14% and 2% to 5% of tannin. In combination they are used to produce the famous Russia leather, whose insect-resisting odour is due to the birch bark. In America this leather is imitated with the American black birch bark (Betula lenta), and also with the oil obtained from its dry distillation.
In the list of materials two have been placed in a subsidiary class because they are a mixture of catechol and pyrogallol tannin. Oak bark produces the best leather known, proving that a blend of the two classes of tannins gives the best results. It is the bark of the coppice oak, and contains 12% to 14% of a reddish-yellow tannage. Valonia is the acorn cup of the Turkish and Greek oak. The Smyrna or Turkish valonia is best, and contains 32% to 36% of an almost white tannin. Greek valonia is greyer in colour, and contains 26% to 30% of tannin. It yields a tough, firm leather of great weight, due to the rapid deposition of a large amount of bloom.
Grinding and Leaching[1] Tanning Materials.—At first sight it would not seem possible that science could direct such a clumsy process as the grinding of tanning materials, and yet even here, the “scientific smashing” of tanning materials may mean the difference between profit and loss to the tanner. In most materials the tannin exists imprisoned in cells, and is also to some extent free, but with this latter condition the science of grinding has nothing to do. If tanning materials are simply broken by a series of clean cuts, only those cells directly on the surfaces of the cuts will be ready to yield their tannin; therefore, if materials are ground by cutting, a proportion of the total tannin is thrown away. Hence it is necessary to bruise, break and otherwise sever the walls of all the cells containing the tannin; so that the machine wanted is one which crushes, twists and cuts the material at the same time, turning it out of uniform size and with little dust.
The apparatus in most common use is built on the same principle as the coffee mill, which consists of a series of segmental cutters; as the bark works down into the smaller cutters of the mill it is twisted and cut in every direction. This is a very good form of mill, but it requires a considerable amount of power and works slowly. The teeth require constant renewal, and should, therefore, be replaceable in rows, not, as in some forms, cast on the bell. The disintegrator is another form of mill, which produces its effect by violent concussion, obtained by the revolution in opposite directions of from four to six large metal arms fitted with projecting spikes inside a drum, the faces of which are also fitted with protruding pieces of metal. The arms make from 2000 to 4000 revolutions per minute. The chief objection to this apparatus is that it forms much dust, which is caught in silken bags fitted to gratings in the drum. The myrobalans crusher, a very useful machine for such materials as myrobalans and valonia, consists of a pair of toothed rollers above and a pair of fluted rollers beneath. The material is dropped upon the toothed rollers first, where it is broken and crushed; then the crushing is finished and any sharp corners rounded off in the fluted rollers.
It must not be thought that now the material is ground it is necessarily ready for leaching. This may or may not be so, depending upon whether the tanner is making light or heavy leathers. If light leathers are being considered, it is ready for immediate leaching, i.e. to be infused with water in preparation of a liquor. If heavy leathers are in process of manufacture, he would be a very wasteful tanner who would extract his material raw. It must be borne in mind that when an infusion is made with fresh tanning material, the liquor begins to deposit decomposition products after standing a day or two, and the object of the heavy-leather tanner is to get this material deposited in the leather, to fill the pores, produce weight and make a firm, tough product. With this end in view he dusts his hides with this fresh material in the layers, i.e. he spreads a layer between each hide as it is laid down, so that the strong liquors penetrate and deposit in the hides. When most of this power to deposit has been usefully utilized in the layers, then the material (which is now, perhaps, half spent) is leached. The light-leather maker does not want a hard, firm leather, but a soft and pliable product; hence he leaches his material fresh, and does not trouble as to whether the tannin deposits in the pits or not.
Whether fresh or partially spent material is leached, the process is carried out in the same way. There are several methods in vogue; the best method only will be described, viz. the “press leach” system.
The leaching is carried out in a series of six square pits, each holding about 3 to 4 tons of material. The method depends upon the fact that when a weak liquor is forced over a stronger one they do not mix, by reason of the higher specific gravity of the stronger one; the weaker liquor, therefore, by its weight forces the stronger liquor downwards, and as the pit in which it is contained is fitted with a false bottom and side duct running over into the next pit, the stronger liquor is forced upwards through this duct on to the next stronger pit. There the process is repeated, until finally the weak liquor or water, as the case may be, is run off the last vat as a very strong infusion. As a concrete example let us take the six pits shown in the figure.
No. 6 is the last vat, and the liquor, which is very strong, is about to be run off. No. 1 is spent material, over which all six liquors have passed, the present liquor having been pumped on as fresh water. The liquor from No. 6 is run off into the pump well, and liquor No. 1 is pumped over No. 2, thus forcing all liquors one forward and leaving pit No. 1 empty; this pit is now cast and filled with clean fishings and perhaps a little new material, clean water is then pumped on No. 2, which is now the weakest pit, and all liquors are thus forced forward one pit more, making No. 1 the strongest pit. After infusing for some time this is run off to the pump well, and the process repeated. It may be noted that the hotter the water is pumped on the weakest pit, the better will the material be spent, and the nearer the water is to boiling-point the better; in fact, a well-managed tanyard should have the spent tan down to between 1% and 2% of tannin, although this material is frequently thrown away containing up to 10% and sometimes even more. There is a great saving of time and labour in this method, since the liquors are self-adjusting.
Testing Tan Liquors.—The methods by which the tanning value of any substance may be determined are many, but few are at once capable of simple application and minute accuracy. An old method of ascertaining the strength of a tan liquor is by means of a hydrometer standardized against water, and called a barkometer. It consists of a long graduated stem fixed to a hollow bulb, the opposite end of which is weighted. It is placed in the liquor, the weighted end sinks to a certain depth, and the reading is taken on the stem at that point which touches “water mark.” The graduations are such that if the specific gravity is multiplied by 1000 and then 1000 is subtracted from the result, the barkometer strength of the liquor is obtained. Thus 1029 specific gravity equals 29° barkometer. This method affords no indication of the amount of tannin present, but is useful to the man who knows his liquors by frequent analysis.
A factor which governs the quality of the leather quite as much as the tannin itself is the acidity of the liquors. It is known that gallic and tannic acids form insoluble calcium salts, and all the other acids present as acetic, propionic, butyric, lactic, formic, &c., form comparatively soluble salts, so that an easy method of determining this important factor is as follows:—
Take a quantity, say 100 c.c., of tan liquor, filter till clear through paper, then pipette 10 c.c. into a small beaker (about 112 in. diameter), place it on some printed paper and note how clear the print appears through the liquor; now gradually add from a burette a clear solution of saturated lime water until the liquor becomes just cloudy, that is until it just loses its brilliancy. Now read off the number of cubic centimetres required in the graduated stem of the burette, and either read as degrees (counting each c.c. as one degree), to which practice at once gives a useful signification, or calculate out in terms of acetic acid per 100 c.c. of liquor, reckoning saturated lime water as 120 normal.
The methods which deal with the actual testing for tannin itself
