Page:EB1911 - Volume 18.djvu/685

From Wikisource
Jump to navigation Jump to search
This page has been proofread, but needs to be validated.
  
MOLECULE
655


that there is no vacuum—that every part of space is full of matter, that there is a universal plenum, and that all motion is like that of a fish in the water, which yields in front of the fish because the fish leaves room for it behind.

Cedere squamigeris latices nitentibus aiunt
Et liquidas aperire vias, quia post loca pisces
Linquant, quo possint cedentes confluere undae.’
Ibid. i. 373.

“In modern times Descartes held that, as it is of the essence of matter to be extended in length, breadth and thickness, so it is of the essence of extension to be occupied by matter, for extension cannot be an extension of nothing.

“ ‘Ac proinde si quaeratur quid fiet, si Deus auferat omne corpus quod in aliquo vase continetur, et nullum aliud in ablati locum venire permittat? respondendum est, vasis latera sibi invicem hoc ipso fore contigua. Cum enim inter duo corpora nihil interjacet, necesse est ut se mutuo tangant, ac manifeste repugnat ut distent, sive ut inter ipsa sit distantia, et tamen ut ista distantia sit nihil; quia omnis distantia est modus extensionis, et ideo sine substantia extensa esse non potest.’—Principia, ii. 18.

“This identification of extension with substance runs through the whole of Descartes’s works, and it forms one of the ultimate foundations of the system of Spinoza. Descartes, consistently with this doctrine, denies the existence of atoms as parts of matter, which by their own nature are indivisible. He seems to admit, however, that the Deity might make certain particles of matter indivisible in this sense, that no creature should be able to divide them. These particles, however, would be still divisible by their own nature, because the Deity cannot diminish his own power, and therefore must retain his power of dividing them. Leibniz, on the other hand, regarded his monad as the ultimate element of everything.

“There are thus two modes of thinking about the constitution of bodies, which have had their adherents both in ancient and in modern times. They correspond to the two methods of regarding quantity—the arithmetical and the geometrical. To the atomist the true method of estimating the quantity of matter in a body is to count the atoms of it. The void spaces between the atoms count for nothing. To those who identify matter with extension, the volume of space occupied by a body is the only measure of the quantity of matter in it.

“Of the different forms of the atomic theory that of R. J. Boscovich may be taken as an example of the purest monadism. According to Boscovich matter is made up of atoms. Each atom is an indivisible point, having position in space, capable of motion in a continuous path, and possessing a certain mass, whereby a certain amount of force is required to produce a given change of motion. Besides this the atom is endowed with potential force, that is to say, that any two atoms attract or repel each other with a force depending on their distance apart. The law of this force, for all distances greater than say the thousandth of an inch, is an attraction varying as the inverse square of the distance. For smaller distances the force is an attraction for one distance and a repulsion for another, according to some law not yet discovered. Boscovich himself, in order to obviate the possibility of two atoms ever being in the same place, asserts that the ultimate force is a repulsion which increases without limit as the distance diminishes without limit, so that two atoms can never coincide. But this seems an unwarrantable concession to the vulgar opinion that two bodies cannot co-exist in the same place. This opinion is deduced from our experience of the behaviour of bodies of sensible size, but we have no experimental evidence that two atoms may not sometimes coincide. For instance, if oxygen and hydrogen combine to form water, we have no experimental evidence that the molecule of oxygen is not in the very same place with the two molecules of hydrogen. Many persons cannot get rid of the opinion that all matter is extended in length, breadth and depth. This is a prejudice of the same kind with the last, arising from our experience of bodies consisting of immense multitudes of atoms. The system of atoms, according to Boscovich, occupies a certain region of space in virtue of the forces acting between the component atoms of the system and any other atoms when brought near them. No other system of atoms can occupy the same region of space at the same time, because before it could do so the mutual action of the atoms would have caused a repulsion between the two systems insuperable by any force which we can command. Thus, a number of soldiers with firearms may occupy an extensive region to the exclusion of the enemy’s armies, though the space filled by their bodies is but small. In this way Boscovich explained the apparent extension of bodies consisting of atoms, each of which is devoid of extension. According to Boscovich’s theory, all action between bodies is action at a distance. There is no such thing in nature as actual contact between two bodies. When two bodies are said in ordinary language to be in contact, all that is meant is that they are so near together that the repulsion between the nearest pairs of atoms belonging to the two bodies is very great.

“Thus, in Boscovich’s theory, the atom has continuity of existence in time and space. At any instant of time it is at some point of space, and it is never in more than one place at a time. It passes from one place to another along a continuous path. It has a definite mass which cannot be increased or diminished. Atoms are endowed with the power of acting on one another by attraction or repulsion, the amount of the force depending on the distance between them. On the other hand, the atom itself has no parts or dimensions. In its geometrical aspect it is a mere geometrical point. It has no extension in space. It has not the so-called property, of impenetrability, for two atoms may exist in the same place. This we may regard as one extreme of the various opinions about the constitution of bodies.

“The opposite extreme, that of Anaxagoras—the theory that bodies apparently homogeneous and continuous are so in reality—is, in its extreme form, a theory incapable of development. To explain the properties of any substance by this theory is impossible. We can only admit the observed properties of such substance as ultimate facts. There is a certain stage, however, of scientific progress in which a method corresponding to this theory is of service. In hydrostatics, for instance, we define a fluid by means of one of its known properties, and from this definition we make the system of deductions which constitutes the science of hydrostatics. In this way the science of hydrostatics may be built upon an experimental basis, without any consideration of the constitution of a fluid as to whether it is molecular or continuous. In like manner, after the French mathematicians had attempted, with more or less ingenuity, to construct a theory of elastic solids from the hypothesis that they consist of atoms in equilibrium under the action of their mutual forces, Stokes and others showed that all the results of this hypothesis, so far at least as they agreed with facts, might be deduced from the postulate that elastic bodies exist, and from the hypothesis that the smallest portions into which we can divide them are sensibly homogeneous. In this way the principle of continuity, which is the basis of the method of Fluxions and the whole of modern mathematics, may be applied to the analysis of problems connected with material bodies by assuming them, for the purpose of this analysis, to be homogeneous. All that is required to make the results applicable to the real case is that the smallest portions of the substance of which we take any notice shall be sensibly of the same kind. Thus, if a railway contractor has to make a tunnel through a hill of gravel, and if one cubic yard of the gravel is so like another cubic yard that for the purposes of the contract they may be taken as equivalent, then, in estimating the work required to remove the gravel from the tunnel, he may, without fear of error, make his calculations as if the gravel were a continuous substance. But if a worm has to make his way through the gravel, it makes the greatest possible difference to him whether he tries to push right against a piece of gravel, or directs his course through one of the intervals between the pieces; to him, therefore, the gravel is by no means a homogeneous and continuous substance.

“In the same way, a theory that some particular substance, say water, is homogeneous and continuous may be a good working theory up to a certain point, but may fail when we come to deal with quantities so minute or so attenuated that their heterogeneity of structure comes into prominence. Whether this heterogeneity of structure is or is not consistent with homogeneity and continuity of substance is another question.

“The extreme form of the doctrine of continuity is that stated by Descartes, who maintains that the whole universe is equally full of matter, and that this matter is all of one kind, having no essential property besides that of extension. All the properties which we perceive in matter he reduces to its parts being movable among one another, and so capable of all the varieties which we can perceive to follow from the motion of its parts (Principia, ii. 23). Descartes’s own attempts to deduce the different qualities and actions of bodies in this way are not of much value. More than a century was required to invent methods of investigating the conditions of the motion of systems of bodies such as Descartes imagined. But the hydrodynamical discovery of Helmholtz that a vortex in a perfect liquid possesses certain permanent characteristics has been applied by Sir W. Thomson (Lord Kelvin) to form a theory of vortex atoms in a homogeneous, incompressible and frictionless liquid.”

The Molecular Structure of Matter

An enormous mass of experimental evidence now shows quite conclusively that matter cannot be regarded as having a continuous structure, but that it is ultimately composed of discrete parts. The smallest unit of matter with which physical phenomena are concerned is the molecule. When chemical phenomena occur the molecule may be divided into atoms, and these atoms, in the presence of electrical phenomena, may themselves be further divided into electrons or corpuscles. It ought accordingly to be possible to explain all the non-electrical and non-chemical properties of matter by treating matter as an aggregation of molecules. In point of fact it is found that the properties which are most easily explained are those connected with the gaseous state; the explanation of these properties in terms of the molecular structure of matter is the aim of the “Kinetic Theory of Gases.” The results of this theory have placed the molecular