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Nov. 11, 1869]
NATURE
45

It is hardly necessary to make any detailed review of the history of the atomic theory. Berzelius made it a starting-point for researches which, on the whole, have been unsurpassed in their practical importance, and engrafted upon it his celebrated electrical doctrine. Davy and Faraday refused to admit it; Laurent and Gerhardt accepted it doubtfully, or in a much modified form. Henry declared that it did not rest on an inductive basis. There can be no doubt, however, that the atomic theory has been accepted by the majority of chemists, as may be seen on even a cursory inspection of the current literature of their science. Our present intention is to give such a summary of the atomic question as may be serviceable to those who take an interest in the discussion at the Chemical Society on Thursday last.

The modern supporters of the atomic theory agree with Dalton in the fundamental suppositions we have given above; but assert that they have a much stronger case. The phenomena of gascous combination and specific heat have indeed changed the numerical aspect of the theory, but not its substance. The simplicity of all the results we have accumulated with respect to combining pro- portions is itself a great argument for the existence of atoms. They all, for example, have the same capacity for heat; they all, when in the gaseous state, have a volume which is an even multiple of that of one part by weight of hydrogen. But bodies in the free or uncombined state-such, in fact, as we see them-more commonly consist of many clusters of atoms (molecules) than of simple atoms. These molecules are determined by the fact that when in the gaseous state they all have the same volume. Again, select a series of chemical equations, in which water is formed, and eliminate between them so as to obtain the smallest proportion of water, taking part in the transformations they represent. It will be found that the number is 18; which necessarily involves the supposition that the oxygen (16) in water (18) is an in- divisible quantity. To put this last point another way: hydrochloric acid, if treated with soda, no matter in what amount, only forms one compound (common salt). Now we know that the action in this case consists in the exchange of hydrogen for sodium. But if hydrogen were infinitely divisible, we ought to be able to effect an in- exhaustible number of such exchanges, and produce an interminable variety of compounds of hydrogen, sodium, and chlorine; hydrochloric acid being the limit on the one side, and common salt (sodic chloride) terminating the other. No such phenomenon occurs; and, since matter must be infinitely or finitely divisible, and has been thus proved not to be the former, it must be the latter. Atoms, therefore, really exist; and chemical combination is in consistent with any other supposition. Those who hold the contrary opinion are bound to produce an alternative theory, which shall explain the facts in some better way.

Now let us hear the plaintiff in reply.

The atomic theory has undoubtedly been of great ser- vice to science, since the laws of definite and multiple pro- portions would probably not have received the attention they deserve, but for being stated in terms of that theory. Yet we must discriminate between these laws, which are the simple expression of experimental facts, and the as- sumption of atoms, which preceded them historically, and therefore has no necessary connection with them. For it was the Greek atomic theory which Dalton revived. Nor has any substance yet been produced by the atomists, which we cannot find means to divide. If, moreover, we have no alternative but to admit the infinite divisibility of matter, even that is consistent with the simple ratios in which bodies combine; for two or more infinites may have a finite ratio. Therefore, the observed simplicity, if used as an argument, cuts both ways. Possibly we are mistaken in connecting the ideas of matter and division at all; at any rate, the connection has never been justified by the opposite side. Again, admitting the argument based on the formation of common salt, the atomic theory docs not tell us why only one third of the hydrogen in tartaric acid can be exchanged for sodium; why, indeed, only a frac- tion of the hydrogen in most organic substances can be so exchanged. Yet, the explanation of the one fact, when discovered, will evidently include that of the other. On the whole, it appears that the atomic theory demands from us a belief in the existence of a limit to division. No such limit has been exhibited to our senses; and the facts themselves do not raise the idea of a limit, which Dalton really borrowed from philosophy. The apparent simplicity of chemical union we do not profess to explain, but to be waiting for any experimental interpretation that may arise. The atomists, in bringing forward their theory, are bound to establish it, and with them lies the onus probandi.

The above are a few broad outlines of the existing aspect of the atomic controversy, and may somewhat assist in forming an estimate of it. The general theoretical tone of the discussion last Thursday must have surprised most who were present. Our own position is necessarily an impartial one; but it will probably be agreed that between the contending parties there is a gulf, deeper and wider than at first appears, and perhaps unprovided with a bridge.


LECTURES TO LADIES.

WHAT is the meaning of the present stir about the "Higher Education of Women"? We have before us announcements of courses of lectures intended to be given during the coming winter to the ladies of Edinburgh, London, Glasgow, Manchester, and Bradford; and we believe that similar courses are to be delivered in several other towns. The organisations under whose auspices these lectures are to be delivered, scem all of them to have come into existence at nearly the same time. Edin- burgh and Professor Masson, so far as we know, have the credit of having taken the lead in the movement; but this was only two winters ago, and none of the towns we have named were more than one year behind.

What is the cause of this sudden and wide-spread demand on the part of our countrywomen for access to a different and, presumably, a higher kind of intellectual culture than has hitherto been within their reach? Or rather, first of all, is the apparent demand a real one? Is It such as to indicate that a real step has been taken, or is likely soon to be taken, towards an improved method and a higher standard of female education in England? Or is it more reasonable to suppose that the interest now mani- fested in the subject will disappear in the same proportion as the novelty of it? For our own part, after making what seems full allowance for the influence which the love