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Page:Popular Science Monthly Volume 56.djvu/266

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252
POPULAR SCIENCE MONTHLY.

were powerfully agitated. We can only speak of this discovery as the stumbling on to an isolated fact, for it was reserved for Volta to establish the generalization that a current is produced in the conductor joining dissimilar metals when the latter are both in contact with a suitable electrolyte (or liquid capable both of conducting electricity and of acting on one, and incidentally also sometimes both, of the metals). Meantime (Du Bois-Reymond observes), "wherever frogs were to be found, and where two different kinds of metal could be procured, everybody was anxious to see the mangled limbs of frogs brought to life in this wonderful way. Physiologists believed that at last they should realize their visions of a vital power, and physicians that no cure was impossible."

Volta first discovered merely the fact of electrification by contact. He wrote to Galvani: "I don't need your frog. Give me two metals and a moist rag, and I will produce your animal electricity. Your frog is nothing but a moist conductor, and in this respect it is inferior to my wet rag!" Nobili, nevertheless, in 1825 proved the existence of galvanic currents in muscles.

Later on Volta invented the "couronne des tasses" (crown of cups), thus at the same time adopting the general form of cell used, with modifications, to-day, and producing the higher electromotive force, or electrical pressure, consequent on the multiplication of the cells in a series battery.

Just before Volta's celebrated communication to the Royal Society, in 1800, Fabroni, of Florence, in discussing Galvani's phenomenon, went to the root of the matter by suggesting that the energy of chemical action was at the bottom of galvanic manifestations, and he was warmly upheld in this contention by Sir Humphry Davy, who, upon the publication of Volta's discoveries, constructed a most elaborate battery with which (apparently about 1806) he produced the arc light between carbon pencils.

In the year referred to, Davy published the results of a series of experiments of enormous significance, among other things of the isolation of the alkali metals, sodium and potassium, whose existence had hitherto not been dreamed of. The simple electrolytic decomposition of water had been accomplished by Nicolson and Carlisle in the last year of the eighteenth century. Sir "W. S. Harris says: "A series of new substances was speedily discovered, the existence of which had never before been imagined. Oxygen, chlorine, and acids were all dragged, as it were, to the positive pole, while metals, inflammable bodies, alkalies, and earths became determined to the negative pole of the battery. When wires connected with each extremity of the new battery were tipped with prepared and well-pointed charcoal, and the points brought near each other,