degeneration applies to the effects of turbulence which always plays a certain havoc in a system. Thus a certain degeneration is associated with the turbulence which is produced when a hot iron is dipped into water, a certain degeneration is associated with the escape of a compressed gas through an orifice, a certain degeneration is associated with the flow of heat from a region of high temperature to a region of low temperature, a certain degeneration is associated with the conversion of work into heat by the rubbing of a coin on a board, and so on.
Reversible Processes
A substance in thermal equilibrium is generally under the influence of external agencies. Thus surrounding substances confine a given substance to a certain region of space, and they exert upon the given substance a definite constant pressure; surrounding substances are at the same temperature as the given substance and according to the atomic theory the molecules of the given substance rebound from the surrounding substance with their motion on the average unchanged; surrounding substances may exert constant magnetic or electric influences on the given substance; and so on. If the external influences which act upon a fluid in thermal equilibrium are made to change very slowly, causing the pressure, volume and temperature of the fluid to pass very slowly through a continuous series of values and in general involving the doing of work upon or by the fluid and the giving of heat to or taking of heat from the fluid, then the fluid will pass slowly through a process consisting of a continuous series of states of thermal equilibrium. Such a process is called a reversible process, for the reason that the fluid will pass through the same series of states in reverse order if the external influences are changed slowly in reverse sense.
Irreversible Processes
When a substance is settling or tending to settle to thermal equilibrium it may be said to undergo a process. Such a process can not be arrested or held at any stage short of complete thermal equilibrium, but it always and inevitably proceeds towards that state. Such a process may, therefore, be called a sweeping process or simply a sweep. The settling of a closed system to thermal equilibrium may be called a simple sweep. For example, the equilibrium of a mixture of oxygen and hydrogen in a closed vessel may be disturbed by a minute spark, and the explosion of the gases together with the subsequent settling of the water vapor to a quiescent state constitutes a simple sweep. The equilibrium of a gas confined under high pressure in one half of a two-chambered vessel may be disturbed by opening a cock which connects the two chambers, and the rush of gas into the empty chamber
