tedious, to find the conditions under which the line appeared. I tried filling the discharge-vessel with all the gases and vapors described in the books on chemistry without success. At last I tried bombarding various substances with cathode rays. Under this treatment the substances give off considerable quantities of gas the greater part of which is hydrogen, carbonic acid or carbon monoxide. When I came to analyze by the positive rays the gases given off in this way, I found that with a large number of substances these gases contained the substances giving the three lines, so that I was now in a position to get this line whenever I wanted it, and investigate the properties of the gas to which it owes its origin. The question of the gases absorbed and given off by solids is an extremely interesting one, and a considerable number of investigations have been made on it. In all these, as far as I know, the method has been to heat the solid to a high temperature, and then measure and analyze the very considerable amount of gas which is driven off by the heating. As far as I know, no experiments have been made in which the gases were driven off by bombardment with cathode rays. This treatment, however, will cause the emission of gas even when ordinary heating fails to do so.
Belloc, who has recently published[1] some interesting experiments on this subject, after spending about six months in a fruitless attempt to get a piece of iron in a state in which it would no longer give off gas when heated, came to the conclusion that, for practical purposes, a piece of iron must be regarded as an inexhaustible reservoir of gas. There are some interesting features about the emission of gas from a heated solid. If the body is kept for a long time in a vacuum at a high temperature, the emission of gas becomes too small to be detected; if after this treatment the temperature is raised considerably, there will be a further copious emission of gas, which again diminishes as the heating continues. After it has fallen to zero, all that is necessary is to raise the temperature again and you will get a fresh supply of gas; and as far as my experience goes, after you have got all the gas you can out of the solid by heating it, you have only to expose it to cathode rays to get a fresh outburst. This effect of increased temperature in renewing the stream of gas from the solid seems to me to be too large to be accounted for merely by an increase in the rate of diffusion of the absorbed gas from the interior to the surface; it seems to be more analogous to the case of the emission of the water of crystallization from some salts. There are some salts, for example, copper sulphate, which when heated lose their water of crystallization in stages;-thus, if the temperature is raised to a certain value, some of the water of crystallization comes off, but the rest remains fixed, and you may keep the salt at this temperature for ever without getting rid of all the water of crystallization; on
- ↑ Ann. de Chimie et de Physique (8), XVIII., p. 569.
