Page:Radio-activity.djvu/223

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containing lithium give a brilliant pink colour. The calcium and barium salts fluoresce with a deep green light, and the sodium compound with a lemon yellow. The mineral willemite (zinc silicate) was recently found by Kunz to be an even more sensitive means of detecting the presence of the radiations than platinocyanide of barium. It fluoresces showing a beautiful greenish colour, and a piece of mineral exposed to the action of the rays appears quite translucent. The crystals of the platinocyanides of barium and lithium are especially suited for showing the action of the γ rays, and, in this respect, are superior to willemite.

A very striking effect is shown by the mineral kunzite—a new variety of spodumene discovered by Kunz[1]. This is a transparent gem like crystal, often of very large size, which glows with a beautiful reddish colour under the action of the β or γ rays, but does not appear to be sensitive to the [Greek: alpha] rays. The luminosity extends throughout the crystal, but is not so marked as in the platinocyanides or willemite. The mineral sparteite[2], a form of calcite containing a few per cent. of manganese, has been found by Ambrecht to fluoresce with a very deep orange light under the β and γ rays. The colour appears to depend on the intensity of the rays, and is deeper close to the radium than at some distance away.

If kunzite and sparteite are exposed to the action of the cathode rays in a vacuum tube, the colour is different from that produced by the radium rays. The former appears a deep yellow, instead of the deep red observed with the radium rays.

The different actions of the radium rays on these fluorescent substances can be illustrated very simply and beautifully by the following experiment. A small U tube is filled with fragments of the fluorescent substance arranged in layers. The U tube is immersed in liquid air and the emanation from about 30 mgrs. of radium bromide is condensed in the tube. On closing the tube and removing it from the liquid air, the emanation distributes itself uniformly in the tube. The shades of colour produced in the different substances are clearly seen.

It is observed that all the crystals increase in luminosity for several hours, on account of the excited activity produced

  1. Kunz and Baskerville, Amer. Journ. Science XVI. p. 335, 1903.
  2. See Nature, p. 523, March 31, 1904.