It was not found convenient in the experiments to determine the activity of the emanation along the cylinder, but an equivalent method was used which depends upon measuring the distribution of "excited activity," produced along a central rod AB, which is charged negatively. It will be shown later (section 177) that the amount of excited activity at any point is always proportional to the amount of emanation at that point. The distribution of "excited activity" along the central rod from the plate C upwards thus gives the variation of p for the emanation along the tube. In the experiments, the cylinder was filled with dry air at atmospheric pressure and was kept at a constant temperature. The central rod was charged negatively and exposed from one to two days in the presence of the emanation. The rod was then removed, and the distribution of the excited activity along it determined by the electric method. It was found that the amount of excited activity fell off with the distance x according to an exponential law, falling to half value in about 1·9 cms. This is in agreement with the above theory. Since the activity of the emanation falls to half value in 1 minute, λ = ·0115. The value K = ·09 was deduced from the average of a number of experiments. This is a slightly greater value than K = ·07, obtained for the radium emanation, but the results show that the two emanations do not differ much from one another in molecular weight. Makower (loc. cit.) compared the rates of diffusion of the thorium and radium emanation through a porous plate, and concluded that the two emanations were of about the same molecular weight, thus confirming the results obtained by the above method. Diffusion of the Emanation into Liquids.
164. Experiments have been made by Wallstabe[1] on the
coefficient of diffusion of the radium emanation into various liquids.
The radium emanation was allowed to diffuse into a closed reservoir,
containing a cylinder of the liquid under observation. The cylinder
- ↑ Wallstabe, Phys. Zeit. 4, p. 721, 1903.
