thorium. The matter was dissolved off an active platinum plate by hydrochloric acid, and then electrolysed between platinum electrodes. The cathode was very active, but there was no trace of activity on the anode. The cathode lost its activity at a rate much faster than the normal. With an amalgamated zinc cathode on the other hand, the rate of decay was normal. When an active solution of hydrochloric acid was electrolysed with an electromotive force smaller than that required to decompose water, the platinum became active. The activity decayed to half value in 4·75 hours while the normal fall is to half value in 11 hours. These results point to the conclusion that the active matter is complex and consists of two parts which have different rates of decay of activity, and can be separated by electrolysis.
Under special conditions it was found possible to make the anode active. This was the case if the anion attached itself to the anode. For example, if an active hydrochloric solution was electrolysed with a silver anode, the chloride of silver formed was strongly active and its activity decayed at a normal rate. The amount of activity obtained by placing different metals in active solutions for equal times varied greatly with the metal. For example, it was found that if a zinc plate and an amalgamated zinc plate, which show equal potential differences with regard to hydrochloric acid, were dipped for equal times in two solutions of equal activity, the zinc plate was seven times as active as the other. The activity was almost removed from the solution in a few minutes by dipping a zinc plate into it. Some metals became active when dipped into an active solution while others did not. Platinum, palladium, and silver remained inactive, while copper, tin, lead, nickel, iron, zinc, cadmium, magnesium, and aluminium became active. These results strongly confirm the view that excited activity is due to a deposit of active matter which has distinctive chemical behaviour.
G. B. Pegram[1] has made a detailed study of the active deposits obtained by electrolysis of pure and commercial thorium salts. The commercial thorium nitrate obtained from P. de Haen gave, when electrolysed, a deposit of lead peroxide on the anode. This deposit was radio-active, and its activity decayed at the normal rate of the excited activity due to thorium. From solutions of
- ↑ Pegram, Phys. Review, p. 424, Dec. 1903.
