investigation necessarily requires much time ; many
of the changes, more especially the chemical ones,
can only be brought about by brilliant sunlight,
acting for a considerable length of time. The
report is therefore divided into two sections, the
first of which is now presented, dealing especially
with the nature of the optical changes.
As this is a question of very great interest to
water-colour painters, the following resume of the
report may not prove uninteresting.
It was expedient in conducting the experiments to
choose the light which would most readily adapt
itself to giving a clue as to which colours were
affected by exposure in a time which would be
measured by months instead of years. After deli-
berate consideration, the experimenters decided to
avail themselves of as much sunlight as could be
secured, together with the diffused and sky light
when sunshine was absent. Some writers have
declined to accept deductions as to the fading of
pigments when exposed to the bright liglit of the
sun, but they have never given any serious reasons
for their doing so. Their arguments have usually
been based upon their own convictions rather than
on experimental proof of any kind, or if experi-
mental proof has been quoted from other writers,
half the truth or more is most frequently and pro-
bably unwittingly concealed.
A popular fallacy is that if the light be very
feeble, a bleachable colour, no matter how long it
may be exposed, will not fade. It has been fully
proved by experiment that, if a certain tint be
exposed to an intensity of light, say of 100, and is
bleached by it in, say one hour, a similar tint,
exposed to an intensity of 1, would, with 100 hours
exposure, undergo the same bleaching.
As to the liglit to which pictures are ordinarily
exjDosed in a room, there is no doubt that they are,
as a rule, carefully protected from direct sunlight,
but it is nevertheless true that the greater portion
of the light they receive is reflected sunlight. On
a bright day clouds reflect sunlight, and on a dull
day the principal part of the diffused light is also
sunlight, which is reflected according to the laws
of geometrical optics from particle to particle, a
certain percentage eventually reaching the earth
througji the clouds. There is of course also a fair
proportion of the light due to the upper sky, and this
light is bluer than reflected or diffused and weakened
sunlight. In cases where the windows of a gallery
are in the vertical walls, and have an uninterrupted
view of the horizon, the blue light reflected is com-
paratively small, the light near the horizon being
distinctly more like sunlight than is that nearer the
zenith. In galleries lighted like those at South
Kensington by skylights, the light to which pictures
are subjected is on the whole bluer.
The artificial lights to which water-colours are
exposed are gas-light, the arc and incandescence
electric liglits, and, as will be seen by the results, the
first and last of these are very deficient in blue rays.
Doubtless, to the eye, the hue of the lights men-
tioned above differ considerably ; but unless the
cause of the difference had been tracked out experi-
mentally, and with scientific exactness, it would
have been unwise to have selected any one of them
with which to conduct experiments, since the results
obtained with it might not be applicable to any
other. Happily, however, for such work, the spec-
troscopic analysis of light furnishes irrefutable
evidence that, from the results obtained from ex-
posure to one light, correct deductions may be made
as to what would happen* were the exposure made
to another. If, by a prism, we analyse all the
different kinds of light mentioned above, we find
that in the visible spectra so obtained no colour is
absent ; but, if we compare the intensity of the
same colours in the different spectra, we find that
there is a variation.
Since, then, all these sources of light emit the
same rays, but of different intensities, which can be
measured, it follows that if we know which rays are
cliemically active, and the amount of work which,
wlien of a certain intensity, they perform, we can,
from the work done by the light from one source,
deduce the work that would be done by another.
The most perfect manner of noting the action of
light would be to expose the pigments for a given
time to the action of the spectrum formed by an
unvarying source of light, and to measure the
amount of chemical action (fading of the colour in
most cases) which had taken place under every part of
the spectrum. When the relative intensities of the
different parts of the spectra from other sources of
light compared with this standard spectrum were
known, then the length of time during which it
would be necessary to expose the colour to any one
of them to produce that same total effect could be
calculated. Months being often required, however,
even in full sunlight, to effect a visible chemical action
on some of the pigments, resort was therefore had to
the use of coloured glasses, in order to hasten the
investigations, to ascertain the part of the spectrum
which was most active in producing the fading
action. The glasses used were red, green, and blue.
In every case where any fading took place, it was
always found beneath the blue glass, much less
often, and to a far less degree, under the green, and
only twice under the red glass, and was then barely
perceptible.
Page:Scottishartrevie01unse.djvu/183
Jump to navigation
Jump to search
This page needs to be proofread.
THE ACTION OF LIGHT ON WATER-COLOURS
151