Page:The Liquefaction of Gases.djvu/61

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Liquefaction of Gases.
57

Arseniuretted Hydrogen.—This body, liquefied by Dumas and Soubeiran, did not solidify at the lowest temperature to which I could submit it, i.e. not at 166° below 0° Fahr. In the following table of the elasticity of its vapour the marked results are experimental, and the others interpolated:—

Fahr.
°
Atmospheres. Fahr.
°
Atmospheres. Fahr.
°
Atmospheres.
 √ -75 0.94 -30 2.84  √ 10 6.24
-70 1.08  √ -23 3.32  √ 20 7.39
 √ -64 1.26 -20 3.51 30 8.66
-60 1.40 -10 4.30  √ 32 8.95
 √ -52 1.73  √ -5 4.74  √ 40 10.05
-50 1.80  √ 0 5.21  √ 50 11.56
-40 2.28  √ 3 5.56  √ 60 13.19
 √ -36 2.50




The following bodies would not freeze at the very low temperature of the carbonic acid bath in vacuo (-166° Fahr.):—Chlorine, ether, alcohol, sulphuret of carbon, caoutchoucine, camphine or rectified oil of turpentine. The alcohol, caoutchoucine, and camphine lost fluidity and thickened somewhat at -106°, and still more at the lower temperature of -166°. The alcohol then poured from side to side like an oil.

Dry yellow fluid nitrous acid when cooled below 0° loses the greater part of its colour, and then fuses into a white, crystalline, brittle and but slightly translucent substance, which fuses a little above 0° Fahr. The green and probably hydrated acid required a much lower temperature for its solidification, and then became a pale bluish solid. There were then evidently two bodies, the dry acid which froze out first, and then the hydrate, which requires at least -30° below 0° before it will solidify.

The following gases showed no signs of liquefaction