Note.—Additional remarks respecting the Condensation of Gases.
Received February 20,—Read February 20, 1845.
Nitrous oxide.—Suspecting the presence on former occasions of nitrogen in the nitrous oxide, and mainly because of muriate in the nitrate of ammonia used, I prepared that salt in a pure state from nitric acid and carbonate of ammonia previously proved, by nitrate of silver, to be free from muriatic acid. After the nitrous oxide prepared from this salt had remained for some days in well-closed bottles in contact with a little water, I condensed it in the manner already described, and when condensed I allowed half the fluid to escape in vapour, that as much as possible of the less condensable portion might be carried off. In this way as much gas as would fill the capacity of the vessels twenty or thirty times or more was allowed to escape. Afterwards the following series of pressures was obtained:—
| Fahr. ° |
Atmospheres. | Fahr. ° |
Atmospheres. | Fahr. ° |
Atmospheres. | ||||||
| -125 | 1.00 | -70 | 4.11 | -15 | 14.69 | ||||||
| -120 | 1.10 | -65 | 4.70 | -10 | 16.15 | ||||||
| -115 | 1.22 | -60 | 5.36 | -5 | 17.70 | ||||||
| -110 | 1.37 | -55 | 6.09 | 0 | 19.34 | ||||||
| -105 | 1.55 | -50 | 6.89 | 5 | 21.07 | ||||||
| -100 | 1.77 | -45 | 7.76 | 10 | 22.89 | ||||||
| -95 | 2.03 | -40 | 8.71 | 15 | 24.80 | ||||||
| -90 | 2.34 | -35 | 9.74 | 20 | 26.80 | ||||||
| -85 | 2.70 | -30 | 10.85 | 25 | 28.90 | ||||||
| -80 | 3.11 | -25 | 12.04 | 30 | 31.10 | ||||||
| -75 | 3.58 | -20 | 13.32 | 35 | 33.40 | ||||||
These numbers may all be taken as the results of experiments. Where the temperatures are not those actually observed, they are in almost all cases within a degree of it, and proportionate to the effects really observed. The departure of the real observations from the numbers given is very small. This table I consider as far more
