Page:The fundamental laws of electrolytic conduction.djvu/19

From Wikisource
Jump to navigation Jump to search
This page has been proofread, but needs to be validated.

MEMOIRS ON THE FUNDAMENTAL

the test paper to be employed. The test paper itself was supported upon a platina spatula, connected either with a discharging train or with the negative wire of the voltaic apparatus, and it consisted of four thicknesses, moistened at all times to an equal degree in a standard solution of hydriodate of potassa.

When the platina wire was connected with the prime conductor of the machine and the spatula with the discharging train, ten turns of the machine had such decomposing power as to produce a pale, round spot of iodine of the diameter of the wire; twenty turns made a much darker mark, and thirty turns made a dark-brown spot, penetrating to the second thickness of the paper. The difference in effect produced by two or three turns, more or less, could be distinguished with facility.

The wire and the spatula were then connected with the voltaic apparatus, the galvanometer being also included in the arrangement; and, a stronger acid having been prepared, consisting of nitric acid and water, the voltaic apparatus was immersed so far as to give a permanent deflection of the needle to the 5 1/3 division, the fourfold moistened paper intervening as before.[1] Then by shifting the end of the wire from place to place upon the test paper, the effect of the current for five, six, seven, or any number of beats of the watch was observed and compared with that of the machine. After alternating and repeating the experiments of comparison many times, it was constantly found that this standard current of voltaic electricity, continued for eight beats of the watch, was equal in chemical effect to thirty turns of the machine; twenty-eight revolutions of the machine were sensibly too few.

Hence it results that both in magnetic deflection and in chemical force, the current of electricity of the standard voltaic battery for eight beats of the watch was equal to that of the machine evolved by thirty revolutions.

It also follows that for this case of electro-chemical decom- position, and it is probable for all cases, that the chemical power, like the magnetic force, is in direct proportion to the absolute quantity of electricity which passes.

Hence arises still further confirmation, if any were required,

7

  1. Of course the heightened power of the voltaic battery was necessary to compensate for the bad conductor now interposed.