Radio-activity/Appendix B
APPENDIX B.
RADIO-ACTIVE MINERALS.
Those natural mineral substances which possess marked radio-active
properties have been found to contain either uranium or thorium,
one of these elements being always present in sufficient proportion
readily to permit its chemical separation and identification by the
ordinary analytical methods[1].
A large number of uranium and thorium minerals are known at the present time, but they are for the most part found very sparingly, and some of them have been observed to occur only in a single locality. The chief commercial sources of uranium are uraninite, gummite, and carnotite, while thorium is obtained almost exclusively from monazite.
Rutherford and Soddy (Phil. Mag. 65, 561 (1903)), were the first to call attention to the important fact that the relations between the various radio-active substances and the other elements could best be determined from the study of the natural minerals in which these bodies occur, since these minerals represent mixtures of extreme antiquity, which have remained more or less undisturbed for almost countless ages. In dealing with these matters, however, it is highly important that we bring to our aid the data furnished by geology and mineralogy, from which it is often possible to determine the relative ages of the different substances with at least a rough degree of approximation. Thus, for example, if a certain mineral occurs as a primary constituent of a rock of remote geological period, it can safely be assumed that its age is greater than that of a similar or different mineral occurring in a later formation. It is, moreover, quite evident that those minerals which are obviously produced by the decomposition and alteration of the primary minerals, through the action of percolating water and other agencies acting from the surface down-*
- ward, are of less antiquity than the primary minerals from which
they originated. Through the application of these considerations it should, in general, be possible to arrange the various minerals roughly in the order of their probable ages.
The most familiar and widely known uranium mineral is uraninite, commonly called pitchblende, which consists essentially of uranium dioxide (UO_{2}), uranium trioxide (UO_{3}), and lead oxide (PbO), present in varying proportions. The uraninites can be distinguished as primary, namely, those which occur as a primary constituent of pegmatitic dikes and coarse granites, and secondary, when they occur in metalliferous veins associated with the sulphides of silver, lead, copper, nickel, iron, and zinc. The former varieties are quite frequently crystalline in character, contain a larger proportion of the rare earths and helium, and have a higher specific gravity than the latter, which are always massive and botryoidal.
The following are the most prominent localities in which primary uraninites occur:
1. North Carolina, U.S.A. (especially in Mitchell and Yancey counties). The uraninite is found in a coarse pegmatitic dike which is mined for the mica constituent. The associated feldspar of the dike is considerably decomposed through the action of meteoric waters and gases, and the uraninite itself is largely altered into the secondary minerals gummite and uranophane through the same agencies. Among the associated primary minerals are allanite, zircon, columbite, samarskite, fergusonite and monazite, while the secondary minerals include gummite, thorogummite, uranophane, autunite, phosphuranylite, hatchettolite, and cyrtolite. The geological period of this formation is difficult to establish with certainty, but is stated to be perhaps Archean, or possibly to correspond with the close of the Ordovician or with the Permian.
2. Connecticut, U.S.A. The best known localities are Glastonbury, where the uraninite is found in the feldspar quarries, and Branchville, where it occurs in an albitic granite. Both of these localities have furnished fine crystals. The geological period probably corresponds with the close of the Ordovician or Carboniferous eras, and is stated to be certainly Post-Cambrian and Pre-Triassic. Among the associated minerals are (primary) columbite, (secondary) torbernite and autunite.
3. Southern Norway, particularly in the neighbourhood of Moss. Here uraninite occurs in the augite-syenite and pegmatite. The varieties found are known as cleveite and bröggerite, and among the primary associated minerals are orthite, fergusonite, monazite, and thorite. The period is stated to be Post-Devonian.
4. Llano County, Texas. The variety of uraninite known as nivenite is found here in a quartzose pegmatite, associated with the primary minerals gadolinite, allanite and fergusonite, and the secondary minerals cyrtolite, yttrialite, gummite, and thorogummite.
Secondary uraninite is found at Johanngeorgenstadt, Marienberg and Schneeberg in Saxony, at Joachimsthal and Přibam in Bohemia, at Cornwall in England, and at Black Hawk, Colorado, and in the Black Hills, South Dakota, in the United States. The exact geological period of most of these secondary occurrences is somewhat uncertain, but they are undoubtedly very much later than the primary occurrences mentioned above.
As a matter of general interest the analysis of a typical primary uraninite (No. 1) and of a typical secondary uraninite (No. 2) is given below[2]:
No. 1 No. 2
Glastonbury, Conn. Johanngeorgenstadt, Saxony
Sp. Gr. 9·59 6·89
UO_{3} 26·48 60·05
UO_{2} 57·43 22·33
ThO_{2} 9·79 . . .
CeO_{2} 0·25 . . .
La_{2}O_{3} 0·13 . . .
Y_{2}O_{3} 0·20 . . .
PbO 3·26 6·39
CaO 0·08 1·00
He und. und.
H_{2}O 0·61 3·17
Fe_{2}O_{3} 0·40 0·21
SiO_{2} 0·25 0·50
Al_{2}O_{3} . . . 0·20
Bi_{2}O_{3} . . . 0·75
CuO . . . 0·17
MnO . . . 0·09
MgO . . . 0·17
Na_{2}O . . . 0·31
P_{2}O_{5} . . . 0·06
SO_{3} . . . 0·19
As_{2}O_{3} . . . 2·34
Insoluble 0·70 . . .
The following list comprises the more important radio-active minerals, with their approximate chemical composition and some notes
on their occurrence and probable origin. Name Composition Remarks
Uraninite Oxides of uranium and lead. Occurs primary as a
Cleveite Usually contains thorium, constituent of rocks and
Bröggerite other rare earths and helium secondary in veins with
Nivenite Uranium 50-80% metalliferous sulphides
Pitchblende Thorium 0-10%
Gummite (Pb, Ca) U_{3}SiO_{12} . 6H_{2}O? An alteration product of
Uranium 50-65% uraninite. Formed by the
action of percolating waters
Uranophane CaO . 2UO_{3} . 2SiO_{2} . 6H_{2}O
Uranotil Uranium 44-56% An alteration product of
uraninite through gummite
Carnotite A vanadate of uranium and Occurs as a secondary
potassium mineral impregnating a
Uranium 42-51% porous, sedimentary sandstone.
Found in Colorado
and Utah
Uranosphaerite Bi_{2}O_{3} . 2UO_{3} . 3H_{2}O Alteration product of
Uranium 41% other uranium minerals
Torbernite CuO . 2UO_{3} . P_{2}O_{5} . 8H_{2}O " "
Cuprouranite Uranium 44-51% " "
Autunite CaO . 2UO_{3} . P_{2}O_{5} . 8H_{2}O " "
Calciouranite Uranium 45-51% " "
Uranocircite BaO . 2UO_{3} . P_{2}O_{5} . 8H_{2}O " "
Uranium 46%
Phosphuranylite 3UO_{3} . P_{2}O_{5} . 6H_{2}O " "
Uranium 58-64%
Zunerite CuO . 2UO_{3} . As_{2}O_{5} . 8H_{2}O " "
Uranium 46%
Uranospinite CaO . 2UO_{3} . As_{2}O_{5} . 8H_{2}O " "
Uranium 49%
Walpurgite 5Bi_{2}O_{3} . 3UO_{3} . As_{2}O_{5} . 12H_{2}O " "
Uranium 16%
Thorogummite UO_{3} . 3ThO_{2} . 3SiO_{2} . 6H_{2}O? A variety of gummite
Uranium 41%
Thorite ThSiO_{4} A primary constituent of
Orangite Uranium 1-10% pegmatite dikes
Uranothorite Thorium oxide 48-71%
Thorianite Oxide of thorium, uranium, Occurs as a primary constituent
the rare earths and lead. of a pegmatite
Contains a relatively large dike in Ceylon. Geological
proportion of helium. age probably Archean
Uranium 9-10%
Thorium oxide 73-77%
Samarskite Niobate and tantalate of Primary constituent of
rare earths pegmatite dikes
Uranium 8-10%
Fergusonite Metaniobate and tantalate " "
of rare earths
Uranium 1-6%
Euxenite Niobate and titanate of " "
rare earths
Uranium 3-10%
Monazite Phosphate of the rare " "
earths, chiefly cerium
Uranium 0·3-0·4%