production. The thorium compounds very readily absorb water-vapour, which is slowly given off at low pressures, and in consequence some of the emanation is carried out of the vessel with the water-vapour.
Curie and Debierne[1] found that both the amount of excited activity produced in a closed vessel containing active samples of radium, and also the time taken to reach a maximum value, were independent of the pressure and nature of the gas. This was true in the case of a solution down to the pressure of the saturated vapour, and in the case of solid salts to very low pressures. When the pump was kept going at pressures of the order of ·001 mm. of mercury, the amount of excited activity was much diminished. This was probably not due to any alteration of the rate of escape of the emanation, but to the removal of the emanation by the action of the pump as fast as it was formed.
Since the amount of excited activity, when in a state of radio-active equilibrium, is a measure of the amount of emanation producing it, these results show that the amount of emanation present when the rate of production balances the rate of decay is independent of the pressure and nature of the gas. It was also found that the time taken to reach the point of radio-active equilibrium was independent of the size of the vessel or the amount of active matter present. This proves that the state of equilibrium cannot in any way be ascribed to the possession by the emanation of any appreciable vapour pressure; for if such were the case, the time taken to reach the equilibrium value should depend on the size of the vessel and the amount of active matter present. The results are, however, in agreement with the view that the emanation is present in minute quantity in the tube, and that the equilibrium is governed purely by the radio-active constant λ, the constant of decay of activity of the emanation. This has been seen to be the same under all conditions of concentration, pressure and temperature, and, provided the rate of supply of the emanation from the active compound is not changed, the time-rate of increase of activity to the equilibrium value will always be the same, whatever the size of the vessel or the nature and pressure of the surrounding gas.
- ↑ Curie and Debierne, C. R. 133, p. 931, 1901.
